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Absence of Diffusively Free Radical Cation Intermediates in Reactions of β-(Phosphatoxy)alkyl Radicals

✍ Scribed by Choi, Seung-Yong; Crich, David; Horner, John H.; Huang, Xianhai; Martinez, Felix N.; Newcomb, Martin; Wink, Donald J.; Yao, Qingwei


Book ID
126918255
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
95 KB
Volume
120
Category
Article
ISSN
0002-7863

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## Abstract By using the ESR and CIDNP methods the formation of free radicals in the reaction of nucleophilic and electrophilic substitution is proved. The role of free radicals in the mechanism of these reactions is discussed.