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ChemInform Abstract: Chemistry of β-(Phosphatoxy)alkyl and β-(Acyloxy)alkyl Radicals. Migration Reactions: Scope and Stereoselectivity of β-( Phosphatoxy)alkyl Rearrangement. Mechanism of β-(Phosphatoxy) alkyl and β-(Acyloxy)alkyl Migration.

✍ Scribed by D. CRICH; Q. YAO; G. F. FILZEN

Book ID
112029514
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
27
Category
Article
ISSN
0931-7597

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β-(Phosphatoxy)alkyl and β-(acyloxy)alky
β-(Phosphatoxy)alkyl and β-(acyloxy)alkyl radical migrations studied by laser flash photolysis
✍ Seung-Yong Choi; David Crich; John H. Horner; Xianhai Huang; Martin Newcomb; Pat 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 700 KB

A number of ~(phosphatoxy)alkyl and ~(acyloxy)alkyl radicals have been ~nenu~ by laser flash photolysis of the corresponding Barton PTOC esters. Time resolved studies permitt~ the determination of rate constants and kinetic parameters for their rearrangement in benzene, THF, and acetonitrile. Migrat