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Abnormal decay kinetics of the excited state of ruthenium trisbipyridyl ions in surfactant solutions

โœ Scribed by J.H. Baxendale; M.A.J. Rodgers

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
256 KB
Volume
72
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The charactertsttcs of the steady-state quenctung of the emlsslon from Ru(blpy)z+ m solutions contammg sodmm dodecyl sulphate (SDS) at concentrations below the cntuxd micelIe concentratton mdtcates that Ru(brpy)z * forms coniple\es ~rth SDS which contam several Ru(brpy)$+. The abnormally fast decay of the enussron seen on laser ekcitatron of these systems rs conststcnt wtth the selfquenchtng of cxctted states produced m the same cluster of Ru(brpy)$ -.

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