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Ab-initio-Untersuchungen zu Struktur und Stabilität von [R3SiAl]4, R = H, Me, tBu

✍ Scribed by Uwe Schneider; Prof. Dr. Reinhart Ahlrichs; Dr. Hans Horn; Ansgar Schäfer


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
409 KB
Volume
104
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Ab Initio Investigations of Structure an
✍ Dipl.-Chem. Uwe Schneider; Prof. Dr. Reinhart Ahlrichs; Dr. Hans Horn; Dipl.-Che 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 446 KB

The second largest molecule so far dealt with by ab initio methods is the tetrameric Al^1^ compound [__t__Bu~3~SiAl]~4~. The calculations yielded structure parameters that are in agreement with those of related compounds, and showed that, above all, the lack of π backbonding in the monomer explains

Synthese, Struktur und Reaktivität von f
✍ L. Weber; C. A. Mast; M. H. Scheffer; H. Schumann; S. Uthmann; R. Boese; D. Bläs 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 198 KB 👁 1 views

Professor Gerhard Fritz zum 80. Geburtstag gewidmet Inhaltsu È bersicht. Bei der Reaktion a È quimolarer Mengen an [(g 5 -C 5 Me 5 )(CO) 2 RuSb(SiMe 3 ) 2 ] (1 b) mit Carbonsa È urechloriden RC(O)Cl (R = tBu, Ph, 1-Adamantyl) werden die Acyl(trimethylsilyl)stibanido-Komplexe [(g 5 -C 5 Me 5 ) (CO) 2