Ab initio study of the potential energy surface and product branching ratios for the reaction of O(1D) with CH3CH2F
โ Scribed by Chongfu Song; Zhimei Tian; Quanxin Li; Tianjing He
- Book ID
- 108285978
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 636 KB
- Volume
- 910
- Category
- Article
- ISSN
- 0166-1280
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๐ SIMILAR VOLUMES
Using a pulse-radiolysis transient UV-VIS absorption system, rate constants for the reactions of F atoms with CH 3 CHO (1) and CH 3 CO radicals with O 2 (2) and NO (3) at 295 K and 1000 mbar total pressure of SF 6 was determined to be By monitoring the for-ฯช12 ฯช11 3 ฯช1 ฯช1 (4.4 ฯฎ 0.7) ฯซ 10 , and k ฯญ
The mechanism of electronic quenching of the A 2A state of CH by ground-state H, is qualitatively investigated by calculating the appropriate potential energy surfaces. It is shown that the appearance of an early potential barrier of 0.15 eV and of a late barrier of 0.6 eV on the potential energy su