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Ab Initio Study of the Effect of Heteroatoms and Bulky Substituents on the Strain Energies of Cyclosilanes

✍ Scribed by Kudo, Takako; Akiba, Satoru; Kondo, Yoriko; Watanabe, Hamao; Morokuma, Keiji; Vreven, Thom

Book ID
121877533
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
56 KB
Volume
22
Category
Article
ISSN
0276-7333

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## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc