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Ab initio studies on the decomposition kinetics of CF3OCF2O radical

✍ Scribed by Hari Ji Singh; Bhupesh Kumar Mishra

Book ID
106240299
Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
222 KB
Volume
17
Category
Article
ISSN
1610-2940

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πŸ“œ SIMILAR VOLUMES

Kinetics of the thermal decomposition of
Kinetics of the thermal decomposition of bis(trifluoromethyl) peroxydicarbonate, CF3OC(O)OOC(O)OCF3
✍ Maximiliano A. Burgos Paci; Gustavo A. ArgΓΌello; PlΓ‘cido GarcΓ­a; Helge Willner πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 84 KB

## Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N~2~ or CO. An activation energy of 28.5 kca