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A Quantum Mechanical Study of the Decomposition of CF 3 OCF 3 and CF 3 CF 2 OCF 2 CF 3 in the Presence of AlF 3

✍ Scribed by Jiang, Bangwu; Keffer, David J.; Edwards, Brian J.


Book ID
127396209
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
159 KB
Volume
112
Category
Article
ISSN
1089-5639

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Rate constants for the reactions of OH r
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The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine