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Ab initio studies on carbenes; singlet and triplet conformers and vibrational spectra of hydroxy-, dihydroxy- and methylhydroxy-carbene

✍ Scribed by M. Räsänen; T. Raaska; H. Kunttu; J. Murto

Book ID
113257508
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
760 KB
Volume
208
Category
Article
ISSN
0166-1280

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Dependence of the singlet-triplet splitt
Dependence of the singlet-triplet splitting in heterosubstituted carbenes on the heteroatom electronegativity and conformation
✍ David Feller; Weston Thatcher Borden; Ernest R. Davidson 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 527 KB

Rccewed 26 Deccmbet 1979 it IS Shown by ab motto cakulatlons and by sesmquantttative arguments that along the sequence C@Wt)z, C(QH)z, CFz, C(FH)$+ the smplet-trip%% gap decreases, due to decreased TT bonding, as the substrtuent electronegativlty mcreases.