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Dependence of the singlet-triplet splitting in heterosubstituted carbenes on the heteroatom electronegativity and conformation

✍ Scribed by David Feller; Weston Thatcher Borden; Ernest R. Davidson

Book ID: 103019606
Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 527 KB
Volume: 71
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85282-1

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✦ Synopsis

Rccewed 26 Deccmbet 1979 it IS Shown by ab motto cakulatlons and by sesmquantttative arguments that along the sequence C@Wt)z, C(QH)z, CFz, C(FH)$+ the smplet-trip%% gap decreases, due to decreased TT bonding, as the substrtuent electronegativlty mcreases.

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