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Ab Initio Studies of the Radical Cation Diels−Alder Reaction

✍ Scribed by Haberl, Udo; Wiest, Olaf; Steckhan, Eberhard


Book ID
120328107
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
104 KB
Volume
121
Category
Article
ISSN
0002-7863

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The intramolecular cation radical diels-
✍ Bijan Harirchian; Nathan L Bauld 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 181 KB

The first examples of intramolecular cation radical Die&-Alder reactions have been established using trienes which cyclize to hydroindane systems. The extremely high endo stereoselectivity characteristic of the cation radical Diels-Alder reaction is effectively exploited to generate trans-hydroinda