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Ab Initio and Resonance Raman Studies of Hexafluoro-1,3-butadiene

✍ Scribed by Foley, Mary S. C.; Braden, Dale A.; Hudson, Bruce S.; Zgierski, Marek Z.

Book ID
127346362
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
228 KB
Volume
101
Category
Article
ISSN
1089-5639

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The radical cation of hexafluoro-1,3-but
The radical cation of hexafluoro-1,3-butadiene: An ESR study
✍ M. Shiotani; H. Kawazoe; J. Sohma πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 401 KB

Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup