Synthesis and characterisation of a new
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Erwan Galardon; Michael Lukas; Paul Le Maux; Gérard Simonneaux
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Article
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1999
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Elsevier Science
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French
⚖ 205 KB
The preparation of a new chiral porphyrin bearing eight optically active pickets, four on each side of the porphyrin plane is described. Chiral recognition in the complexation of racemic isocyanide to the ruthenium compound leads to the formation of three stereoisomers with low stereoselectivity (15