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A very efficient system for alkene epoxidation by hydrogen peroxide: catalysis by manganese-porphyrins in the presence of imidazole

✍ Scribed by Renaud, Jean-Paul; Battioni, Pierrette; Bartoli, Jean Fran�ois; Mansuy, Daniel


Book ID
120073188
Publisher
The Royal Society of Chemistry
Year
1985
Tongue
English
Weight
259 KB
Volume
13
Category
Article
ISSN
0022-4936

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## Epoxidation of various olefins is achieved by Mm-n-butylammarium periodate in the. preamce of manganese (III) meso-tetraphenylporphyrin and imidamle in CH$l,. with high selectivity and yield under mild conditions. The modeling of cytochrome P-450 class of enzymes with synthetic metalloporphyrin