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Ammonium acetate as a very simple and efficient cocatalyst for manganese porphyrin-catalysed oxygenation of hydrocarbons by hydrogen peroxide

✍ Scribed by Thellend, Annie; Battioni, Pierrette; Mansuy, Daniel


Book ID
121187280
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
289 KB
Volume
9
Category
Article
ISSN
0022-4936

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πŸ“œ SIMILAR VOLUMES


Efficient stereoselective oxygenation of
✍ John R. Lindsay Smith; Georgiy B. Shul'pin πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 233 KB

The dinuclear manganese complex [LMnrV(O)3MnVeL](PF6)2, where L is 1,4,7-trimethyl-l,4,7-triazacyclononane, catalyses the oxygenation ofalkanes by peroxyacetic acid or by H202 in the presence of acetic acid to give alkanols, alkanones and alkyl hydroperoxides. The reactions can give large turnovers