𝔖 Bobbio Scriptorium
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A versatile intermediate for the synthesis of pyranoquinone antibiotics

✍ Scribed by Kraus, George A.; Shi, Jianmin; Reynolds, Don

Book ID
126977743
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
253 KB
Volume
55
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

A catalytic asymmetric synthesis of a ve
A catalytic asymmetric synthesis of a versatile intermediate for phorbol derivatives
✍ Hideaki Sato; Yun Sik Kim; Masakatsu Shibasaki πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 242 KB

A catalytic asynunetric cyclopropanation of enol silyl ether 9 gave the laetonΒ’ 3 in up to 78% eΒ’. The lactonΒ’ 3 was then Iransformcd into 2, potentially a very versatile intermediate for phorbol analogs, using an inu'amol~cular nitrile oxide cycloaddition as a key step.