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A Vaulted Biaryl Phosphoric Acid-Catalyzed Reduction of α-Imino Esters: The Highly Enantioselective Preparation of α-Amino Esters

✍ Scribed by Li, Guilong; Liang, Yuxue; Antilla, Jon C.

Book ID
120316909
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
40 KB
Volume
129
Category
Article
ISSN
0002-7863

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✍ Qiang Kang; Zhuo-An Zhao; Shu-Li You 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 77 KB 👁 1 views

## Abstract Chiral phosphoric acids have been identified as highly efficient organocatalysts for the asymmetric transfer hydrogenation of α‐imino esters and amide. Utilizing Hantzsch esters as the hydrogen donor, versatile highly enantioenriched α‐amino esters and their derivatives were obtained wi