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Highly Enantioselective Transfer Hydrogenation of α-Imino Esters by a Phosphoric Acid

✍ Scribed by Qiang Kang; Zhuo-An Zhao; Shu-Li You

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
77 KB
Volume
349
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

Chiral phosphoric acids have been identified as highly efficient organocatalysts for the asymmetric transfer hydrogenation of α‐imino esters and amide. Utilizing Hantzsch esters as the hydrogen donor, versatile highly enantioenriched α‐amino esters and their derivatives were obtained with up to 98 % ee.

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