A transition-state model for the mikami enantioselective ene reaction

✍ Scribed by E.J. Corey; David Barnes-Seeman; Thomas W. Lee; Steven N. Goodman

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 237 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)01517-7

✦ Synopsis

A logically derived mechani.~tic model is presented for the Mikami enantioselective ene reaction which correedy describes the absolute and relative stereochemistry resulting from transition-state slnlctur~ sltlch as 3 and 5.