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A Total Synthesis of FK-506 1

โœ Scribed by Ireland, Robert E.; Gleason, James L.; Gegnas, Laura D.; Highsmith, Thomas K.

Book ID
126033559
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
909 KB
Volume
61
Category
Article
ISSN
0022-3263

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Studies directed towards the total synth
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โœ Robert E Ireland; Peter Wipf ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 254 KB

The protected C(1) to C(15) segment of FK-506 has been prepared from D-glucose, glycolic and L-pipecolic acid. The novel, highly active immunosuppressive agent FK-506 (1) has attracted considerable attention.1 The biological potency as well as some unique structural features render this 23-membered

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