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A total synthesis of [9′, 10′-3H]-labelled paf-acether

✍ Scribed by Boguslaw Wichrowski; Elie Michel; Françoise Heymans; Jean Roy; Jean-Louis Morgat; Jean-Jacques Godfroid

Publisher
John Wiley and Sons
Year
1983
Tongue
French
Weight
266 KB
Volume
20
Category
Article
ISSN
0022-2135

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✦ Synopsis

l-O-octadecen-[9',1O']-yl 2-0-benzyl sn-glycero-3-phosrylcholine was obtained from I-O-octadecen-[9',10'I-yl sn-glycerol by tritylation, benzylation and phosphorylation with 2-bromoethyl phosphoryl dichloride followed with trimethylamine reaction.

Catalytic tritiation o f the double bond led to labelled "lyso" PAFacether from which PAF-acether with a specific radioactivity between 40 and 5 0 Ci/mmole was obtained by acetylation.

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