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A Time-Resolved SERS Study of the Adsorption and Electrochemical Reduction of 4-Pyridinecarboxaldehyde and 4-(Hydroxymethyl)pyridine

✍ Scribed by Birke, Ronald L.; Shi, Chongtie; Zhang, Wei; Lombardi, John R.


Book ID
127152891
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
232 KB
Volume
102
Category
Article
ISSN
0022-3654

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Competitive adsorption on a polycrystalline Ag electrode was studied for 2-and 4-methylpyridine and pyridme at -0.4 to -0.7 V versus SCE by SERS using the in situ solution exchange method. The steric effect of the CH, group in the 2-position was clearly shown along with the electronic effect of each