✦ LIBER ✦

A time-resolved electron spin resonance study of the triplet states of 1-nitronaphthalene and 1,4-dinitronaphthalene

✍ Scribed by Yasushi Shioya; Mikio Yagi; Jiro Higuchi

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 318 KB
Volume: 154
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87431-7

No coin nor oath required. For personal study only.

✦ Synopsis

Time-resolved ESR spectra have been observed for the lowest excited triplet states of 1-nitronaphthalene and 1,4dinitronaphthalene in EPA at 77 K. The results show that the sublevel preferentially populated by intersystem crossing is T,, in both molecules studied (y is close to the in-plane long axis of the naphthalene ring) and there is a strong vibronic coupling between the 'rot* and the close-lying 'nx* states.

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