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A Three-Center Orbital Interaction in the Diels−Alder Reactions Catalyzed by Lewis Acids

✍ Scribed by Yamabe, Shinichi; Minato, Tsutomu

Book ID
120204215
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
387 KB
Volume
65
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

On the mechanism of Diels—Alder reaction
On the mechanism of Diels—Alder reactions catalyzed by Lewis acids
✍ V. Branchadell; A. Oliva; J. Bertran 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 261 KB

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.