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A thermodynamic study of selective solvation in solvent mixtures

✍ Scribed by Cabot, Rafel; Hunter, Christopher A.

Book ID
118223545
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
256 KB
Volume
8
Category
Article
ISSN
1477-0520

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Using the picosecond spectra-streak method we monitored the dynamics of preferential solvation of a charge-transfer dipole in binary mixtures of solvents strongly different in dielectric constant. The observed slow (0.25-l ns) spectra1 red-shift of the charge-transfer (exciplex) fluorescence is cons