✦ LIBER ✦

A theoretical study of the decomposition of halogenated alkoxy radicals. II. Fluorine extrusion

✍ Scribed by J.C. Rayez; M.T. Rayez; P. Halvick; B. Duguay; J.J. Dannenberg

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 409 KB
Volume: 118
Category: Article
ISSN: 0301-0104
DOI: 10.1016/0301-0104(87)87042-8

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A theoretical study of the abstraction r

A theoretical study of the abstraction reactions of hydroxyl radicals with halogenated aldehydes

✍ M.T. Rayez; D.J. Scollard; J.J. Treacy; H.W. Sidebottom; C. Balestra-Garcia; S. 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 597 KB

The semi-empirical quantum mechanical molecular orbital method PM3 has been used to investigate the nature of the transition states for the reactions of hydroxyl radicals with halogenated aldehydes. For each reaction, the geometric and electronic structures of the transition state corresponding to t

Theoretical study on the gas-phase react

Theoretical study on the gas-phase reactivity of halogenated alkylperoxyl radicals toward alkenes

✍ S. El-Taher 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 273 KB 👁 2 views

The electrophilic additions of hydroperoxyl HO , alkylperoxyl RO , 2 2 and halogenated alkylperoxyl radicals to ethylene were studied using the AM1 and PM3 semiempirical MO methods at the SCFrUHF level. Reactantlike transition states were Ž U . predicted for the title additions. The AM1 activation e

Theoretical study of the competitive dec

Theoretical study of the competitive decomposition and isomerization of 1-hexyl radical

✍ Feng Wang; Dong Bo Cao; Gang Liu; Jie Ren; Yong Wang Li 📂 Article 📅 2009 🏛 Springer 🌐 English ⚖ 602 KB

A theoretical study of the SiCl3 and GeC

A theoretical study of the SiCl3 and GeCl3 radicals

✍ Jerzy Moc; Zdzisz.xl;law Latajka; Henryk Ratajczak 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 590 KB

Theoretical Study on the Thermochemistry

Theoretical Study on the Thermochemistry of Chlorinated and Fluorinated Germanes and Their Radical Fragments

✍ Liming Wang; Jingsong Zhang 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 56 KB 👁 1 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Atmospheric chemistry of HFC-134a: Kinet

Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO

✍ Trine E. Møgelberg; Jens Sehested; Timothy J. Wallington; Ole J. Nielsen 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB

tial . However, questions have been raised concerning the environmental impact of trifluoroacetic acid which is formed from HFC-134a in the atmosphere as a result of the following reaction sequence [7 -10]. (1) (2) (3) (4) Reaction (4) produces CF 3 C(O)F which is hydrolyzed to CF 3 COOH after u