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A theoretical study of the addition of CH3MgCl to chiral α-alkoxy carbonyl compounds

✍ Scribed by Vicent S. Safont; Vicente Moliner; Mónica Oliva; Raquel Castillo; L.R. Domingo; Juan Andrés

Book ID
114142783
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
1011 KB
Volume
426
Category
Article
ISSN
0166-1280

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A theoretical study of malononitrile add
A theoretical study of malononitrile addition to carbonyl compounds
✍ S. El-Taher 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB 👁 2 views

The nucleophilic addition of the malononitrile anion MN to formaldehyde was studied theoretically by the AM1 semiempirical MO method. The addition is found to be endothermic with a late productlike transition state on the reaction coordinate. Additions of MN y to a series of carbonyl compounds were