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A theoretical investigation of the enantioselective hydrogenation mechanism of α-ketoesters

✍ Scribed by Olivier Schwalm; Jacques Weber; Bruno Minder; Alfons Baiker

Book ID
113258202
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
511 KB
Volume
330
Category
Article
ISSN
0166-1280

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Enantioselective hydrogenation of α-keto
Enantioselective hydrogenation of α-ketoesters: comparison of homogeneous and heterogeneous catalysts
✍ Hans-Ulrich Blaser; Hans-Peters Jalett; Felix Spindler 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 660 KB

A case study concerning the development of enantioselective hydrogenation processes for aliphatic a-ketoesters, particularly ethyl 2-oxo-4-phenylbutyrate (1) and ethyl pyruvate (2), using homogeneous Rh-diphosphine and heterogeneous Pt/A1203cinchona catalysts is presented. Important parameters to ob