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Highly Enantioselective Heterogeneously Catalyzed Hydrogenation of α-Ketoesters under Mild Conditions

✍ Scribed by LeBlond, C.; Wang, J.; Liu, J.; Andrews, A. T.; Sun, Y.-K.

Book ID
126029618
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
33 KB
Volume
121
Category
Article
ISSN
0002-7863

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Enantioselective hydrogenation of α-keto
Enantioselective hydrogenation of α-ketoesters: comparison of homogeneous and heterogeneous catalysts
✍ Hans-Ulrich Blaser; Hans-Peters Jalett; Felix Spindler 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 660 KB

A case study concerning the development of enantioselective hydrogenation processes for aliphatic a-ketoesters, particularly ethyl 2-oxo-4-phenylbutyrate (1) and ethyl pyruvate (2), using homogeneous Rh-diphosphine and heterogeneous Pt/A1203cinchona catalysts is presented. Important parameters to ob