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A Theoretical Insight into the Reaction Mechanism of Photochemical Transposition from Pyrazole to Imidazole

โœ Scribed by Su, Ming-Der


Book ID
118261570
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
326 KB
Volume
112
Category
Article
ISSN
1089-5639

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A Theoretical Insight into the Mechanism
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## Abstract DFT calculations on a silverโ€catalysed transsiliranation reaction (silylene transfer from a silirane to an alkene) have shown the key role of a silylenesilver ion in the catalyticcycle. Although the corresponding triflateโ€bound species has previously been detected by NMR and IR spectros