A Theoretical Insight into the Mechanism
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Josรฉ Antonio Mayoral; Sergio Rodrรญguez-Rodrรญguez; Luis Salvatella
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Article
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2010
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John Wiley and Sons
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English
โ 187 KB
๐ 1 views
## Abstract DFT calculations on a silverโcatalysed transsiliranation reaction (silylene transfer from a silirane to an alkene) have shown the key role of a silylenesilver ion in the catalyticcycle. Although the corresponding triflateโbound species has previously been detected by NMR and IR spectros