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A theoretical and experimental investigation of the formation of S2-from CS2by electron impact

✍ Scribed by K. Nagesha; Bhas Bapat; V.R. Marathe; E. Krishnakumar


Publisher
Springer
Year
1997
Tongue
English
Weight
131 KB
Volume
41
Category
Article
ISSN
1434-6060

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πŸ“œ SIMILAR VOLUMES


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Metastnble transitions in CS$ leading to S' + CS and CS++ S under electron impact on CS2 are reported. The predissociation processes able to explain the occurrence of these metastablc transitions are discussed. An interpretation of mrne fast dissociation processes is suggested.

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In qualitative agreement with semi-empirical (MNDO) and ab initio calculations, the electron affinities measured by electron transmission spectroscopy are found to be strongly negative for allene (-1.9 -+ 0.1 eV) and propyne (-2.8 -+ 0.1 eV)