Concomitant [2,3]-sigmatropic rearrangem
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Roland E. Dolle; Chun-Sing Li; Antony N. Shaw
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Article
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1989
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Elsevier Science
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French
β 222 KB
Allylic phenyl and methyl sulfides bearing a strategically positioned electrophilic center have been shown to undergo concomitant C2,31-sigmatropic rearrangement and intramolecular N-alkylation upon oxidative conversion to allylic sulfilimines and treatment with aqueous base. This one-pot transforma