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A tandem allylic alcohol isomerization–aldol condensation catalyzed by Rh and Ru complexes

✍ Scribed by Ramalinga Uma; Maxwell Davies; Christophe Crévisy; René Grée

Book ID
104230457
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
68 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Allylic alcohols react with aldehydes, in an atom economy aldol-type reaction, in the presence of catalytic amounts of various rhodium and ruthenium complexes. This reaction occurs with total regiocontrol under mild conditions, but varying amounts of ketone derived from the competing isomerization reaction are also observed.

📜 SIMILAR VOLUMES

From allylic alcohols to aldols via a no
From allylic alcohols to aldols via a novel, tandem isomerization–condensation catalyzed by Fe(CO)5
✍ Christophe Crévisy; Marina Wietrich; Virginie Le Boulaire; Ramalinga Uma; René G 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 85 KB

Allylic alcohols react with aldehydes, in the presence of catalytic amounts of Fe(CO) 5 and under irradiation, to give mainly aldol products. A small amount of ketone resulting from the classical isomerization process is also isolated. This new aldol-type reaction is a complete atom economy process

ChemInform Abstract: From Allylic Alcoho
ChemInform Abstract: From Allylic Alcohols to Aldols via a Novel, Tandem Isomerization—Condensation Catalyzed by Fe(CO)5.
✍ Christophe Crevisy; Marina Wietrich; Virginie Le Boulaire; Ramalinga Uma; Rene G 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

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