Allylic alcohols react with aldehydes, in an atom economy aldol-type reaction, in the presence of catalytic amounts of various rhodium and ruthenium complexes. This reaction occurs with total regiocontrol under mild conditions, but varying amounts of ketone derived from the competing isomerization r
A Tandem Allylic Alcohol Isomerization—Aldol Condensation Catalyzed by Rh and Ru Complexes.
✍ Scribed by Ramalinga Uma; Maxwell Davies; Christophe Crevisy; Rene Gree
- Book ID
- 101915696
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Allylic alcohols react with aldehydes, in the presence of catalytic amounts of Fe(CO) 5 and under irradiation, to give mainly aldol products. A small amount of ketone resulting from the classical isomerization process is also isolated. This new aldol-type reaction is a complete atom economy process
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