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A systematic study of the stabilities of cyclic boryl anions

✍ Scribed by Chin-Hung Lai; Pi-Tai Chou


Book ID
106240167
Publisher
Springer-Verlag
Year
2009
Tongue
English
Weight
478 KB
Volume
16
Category
Article
ISSN
1610-2940

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## Abstract According to our theoretical approaches, a cyclic boryl anion can act as a Lewis base like its isoelectronic counterpart N‐heterocyclic carbene, reducing the homolytic bond dissociation energy of Bο£ΏH in BH~3~. However, the donating efficiency is affected by the counter cation in both ga