Symbiodinolide is a polyol macrolide isolated from the marine dinoflagellate Symbiodinium sp. in 2007. The C14-C24 fragment of symbiodinolide possessing the 17R/18R/21R absolute configuration, which was obtained as one of the degraded products of symbiodinolide, was synthesized stereoselectively fro
A systematic degradation of zincophorin: a stereoselective synthesis of the C17-C25 fragment
β Scribed by Zelle, Robert E.; DeNinno, Michael P.; Selnick, Harold G.; Danishefsky, Samuel J.
- Book ID
- 126467891
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 747 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
A stereo-controlled radical C C bond formation involving a 5-chloro-5-deoxy-L-idofurano-6,3-lactone derivative and allyltri-n-butyltin/AIBN is described. Further elaboration led to the synthesis of the C13 C19 segment of sanglifehrin A.
The C1-C13 fragment of bistramide A was prepared from 5-hexenoic acid in 15 linear steps and in 16% overall yield. The core 2,6-trans-tetrahydropyran ring was obtained via a kinetically controlled oxa-Michael cyclization from the corresponding chiral a,b-unsaturated hydroxyester. This precursor was