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A Synthetic Route to (±)-Clavizepine through a Dibenzoxepine Intermediate †

✍ Scribed by de la Fuente, M. C.; Castedo, Luis; Domínguez, Domingo

Book ID
127160274
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
205 KB
Volume
61
Category
Article
ISSN
0022-3263

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A strategy using a highly stereoselective Claisen-Ireland rearrangement followed by a Grubbs metathesis afforded in a good overall yield after further functionalisation a potentially synthetic precursor of fumagillin and ovalicin.