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Stereoselective glycosylations via selenium intermediate: A synthetic route to 2′-deoxynucleosides

✍ Scribed by Dong Hoon Lee; Joong Young Kim; Yong Hae Kim

Book ID
112960177
Publisher
Springer
Year
1994
Tongue
English
Weight
157 KB
Volume
17
Category
Article
ISSN
0253-6269

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✍ Willy Picoul; Raquel Urchegui; Arnaud Haudrechy; Yves Langlois 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 244 KB

A strategy using a highly stereoselective Claisen-Ireland rearrangement followed by a Grubbs metathesis afforded in a good overall yield after further functionalisation a potentially synthetic precursor of fumagillin and ovalicin.