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A Synthesis of cis-1,3-Diphenyl-1-butene

✍ Scribed by Goerner, Gordon L.; Hines, Wallis G.

Book ID
126062060
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
294 KB
Volume
70
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Thiosulfonium ions. Methylthiolation of
Thiosulfonium ions. Methylthiolation of 3-methylthio-1-butene and cis- and trans-1-methylthio-2-butene
✍ Jhong K. Kim; Marjorie C. Caserio πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 277 KB

Whereas sulfenyl reagents commonly add to carbon double bonds, addition to sulfur of 3-methylthio-1-butene precedes attack at carbon to give allylic thiosulfonium ions that form reversibly and which rearrange rapidly to trans-2-butenyl analogs. Likewise, rearrangement of cis-to trans-1-methylthio-2