๐”– Bobbio Scriptorium
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Dibutyl cis- and trans-1-butene-1-boronate

โœ Scribed by Gene D. Schaumberg; Stephen Donovan

Book ID
108346888
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
243 KB
Volume
20
Category
Article
ISSN
0022-328X

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๐Ÿ“œ SIMILAR VOLUMES

Thiosulfonium ions. Methylthiolation of
Thiosulfonium ions. Methylthiolation of 3-methylthio-1-butene and cis- and trans-1-methylthio-2-butene
โœ Jhong K. Kim; Marjorie C. Caserio ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 277 KB

Whereas sulfenyl reagents commonly add to carbon double bonds, addition to sulfur of 3-methylthio-1-butene precedes attack at carbon to give allylic thiosulfonium ions that form reversibly and which rearrange rapidly to trans-2-butenyl analogs. Likewise, rearrangement of cis-to trans-1-methylthio-2

Abstraction by hydrogen atoms from ethyl
Abstraction by hydrogen atoms from ethylene, propylene, butene-1, and cis- and trans-butene-2
โœ W. E. Falconer; W. A. Sunder ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 455 KB

The position of abstraction by H atoms from ethylene, propylene, butene-1, and cisand trans-butene-2 and the rates of abstraction relative to addition have been measured at 25ยฐC. From ethylene, abstraction relative to addition was 5 3 X lo-\*. For propylene, butene-1, cis-butene-2, and trans-butene

H2S-promoted thermal isomerization of bu
H2S-promoted thermal isomerization of butene-2 CIS to butene-1 or butene-2 trans around 500ยฐC
โœ C. Richard; A. Boiveaut; R. Martin ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 470 KB

H2S increases the thermal isomerization of butene-2 cis (B,) to butene-1 (B1) and butene-2 trans (Bt) around 500ยฐC. This effect is interpreted on the basis of a free radical mechanism in which buten-2-yl and thiyl free radicals are the main chain carriers. B1 formation is essentially explained by th