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A synthesis of 12,13-epoxytrichothec-9-ene

✍ Scribed by Noriyoshi Masuoka; Tadao Kamikawa

Publisher: Elsevier Science
Year: 1976
Tongue: French
Weight: 176 KB
Volume: 17
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)92925-3

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✦ Synopsis

12,13-Epoxytrlchothec-9-ene L IS a metabollte isolated from Trlchotheclun roseum by Nozoe et al 1 and rts structure was synthetically conflnned by Tatsuno et al 2 In a previous papert we reported that the model cowound 2 was stereoselectlvely cycllsed to 3 by the -slrmlar way as predlcted for the blosynthesls of trlchoderrmn 4

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