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Highly Stereoselective Total Synthesis of (+)-9-epi-Dictyostatin and (–)-12,13-Bis-epi-dictyostatin

✍ Scribed by Chiara Zanato; Luca Pignataro; Andrea Ambrosi; Zhongyan Hao; Chiara Trigili; José Fernando Díaz; Isabel Barasoain; Cesare Gennari

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
552 KB
Volume
2011
Category
Article
ISSN
1434-193X

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A Highly Stereoselective Total Synthesis
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## Abstract The total synthesis of (+)‐9‐__epi__‐dictyostatin (**1b**), a diastereomer of the antimitotic marine‐sponge‐derived macrolide (–)‐dictyostatin (**1a**), was achieved by creating 11 stereogenic centers and 4 stereogenic double bonds with a high level of stereocontrol. The yield for the 2

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