A synthesis and resolution of dl-serine
β Scribed by Shiro Akabori; Theodore T. Otani; Robin Marshall; Milton Winitz; Jesse P. Greenstein
- Book ID
- 118842265
- Publisher
- Elsevier Science
- Year
- 1959
- Tongue
- English
- Weight
- 624 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0003-9861
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract For resolution of chiral compoundβforming substances diastereomeric salt formation is the most important classical separation technique. Diastereomeric salts possess different physical and chemical properties, e.g., solubilities, which facilitate the effective separation via crystalliza
Condensation of monophenylphosphoryl N-carbobenzyloxy DL-serine benzyl ester monosilver salt with the appropriate a-iodo diglyceride by the procedure of Bevan, Malkin, and Tiplady for the synthesis of racemic a-(distearoy1)-phosphatidyl serine, d o r d e d dihexanoyl-, dioctanoyl-, and didecanoyl-DL
## o-Hydro~y-DL-phenylalanine-2-~~C was prepared by the condensation of o-methoxybenzyl chloride and ethyl acetamidocyano-~c e t a t e -2 -~~C and subsequent hydrolysis. The rucemute was resolved by the stereospecijic action of chymotrypsin on the amino acid ethyl ester at pH 5.0 to give the two i