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A surface penning ionization study of NH3ON Ni(111)

โœ Scribed by Ferenc Bozso; Jose M. Arias; Ciaran P. Hanrahan; John T. Yates Jr.; Horia Metiu; Richard M. Martin


Publisher
Elsevier Science
Year
1984
Weight
60 KB
Volume
138
Category
Article
ISSN
0167-2584

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๐Ÿ“œ SIMILAR VOLUMES


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Adsorbed NH is a stable adsorbed intemxdrate formed during hydrzine decomposition in the 285 to 365 K temperature range on the Nt(111) surface. Adsorbed NH is onented nearly perpendicular to the surface with an NH stretching vibralion a~ 3340 cm-'. NH bend at 1260 cm-'. and Ni-N strerch al 620 cm-'.

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We use surface Penning ionization spectroscopy (SPIES) to study the electronic properties of CO and NO adsorbed on Ni(l11). In this experiment an atomic beam contain& J 0 -roundstate and 2 'S He atoms collides with the adsorbate covered Ni(ll1) surface. This causes the transfer of ~20.6 eV energy in