A study of v(CO) frequency shifts in substituted metal carbonyls
โ Scribed by S. besnainou; P. labarbe
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 347 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract An analysis of ^17^O carbonyl chemical shifts of 50 substituted benzaldehydes leads to an empirical equation, ฮด~cal~(^17^O) = 564.0 + ฮฃฮ__o__ + ฮฃฮ__m__ + ฮฃฮ__p__ + __C__, for calculating ^17^O chemical shifts. This equation is based on a linear regression analysis using 11 substituent p
Picosecond infrared saturation-recovery experiments were performed to obtain measurements of the vibrational energy lifetimes ( r, ) of CO( v= 1) vibrations (Y GZ 1920-l 985 cm-' ) of carbonyl-containing metal complexes in dilute, room-temperature solutions. For relaxation of the F,, CO-stretching v