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A study of the 17O carbonyl chemical shifts in substituted benzaldehydes

✍ Scribed by Lidong Li; Linsheng Li

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 91 KB
Volume: 42
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1475

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✦ Synopsis

Abstract

An analysis of ^17^O carbonyl chemical shifts of 50 substituted benzaldehydes leads to an empirical equation, δ~cal~(^17^O) = 564.0 + ΣΔ__o__ + ΣΔ__m__ + ΣΔ__p__ + C, for calculating ^17^O chemical shifts. This equation is based on a linear regression analysis using 11 substituent parameters and leads to good conformity with the expected data. Copyright © 2004 John Wiley & Sons, Ltd.

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