The chloro complexes of cobalt, nickel and copper with 2-phenyl-4-quinoline carboxylic acid have stoichiometry MLCI 2 . The complexes which are polymeric have a stereochemistry in which the metal ion is in a six coordinate environment. The decompositions of the complexes have been studied by thermog
A study of the performance of some first row transition metal complexes of 2-(p. olyl)pyridine and 4-aminoquinaldine as colouring materials for polystyrene
โ Scribed by J.R. Allan; B.R. Carson; D.L. Gerrard; J. Birnie
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 197 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0014-3057
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โฆ Synopsis
The chloro complexes of 2-(p.tolyl)pyridine and 4-aminoquinaldine with cobalt (II), nickel (II) and copper (II) have been prepared. The 4-aminoquinaldine complexes have polymeric octahedral structures. The cobalt and copper complexes of 2-(p.tolyl)pyridine have tetrahedral and tetragonal structures while the nickel complex has a polymeric octahedral structure. The initial decomposition temperatures of the complexes have been studied by thermogravimetry. The performance of the complexes as colouring materials for polystyrene has been investigated{ weather resistance, light fastness, migration resistance and heat stability have been considered.
๐ SIMILAR VOLUMES
A~tract--Complexes have been prepared by the reactions of 2,6-diaminopyridine and 4-aminobenzoyl hydrazide with the chlorides of cobalt, nickel and copper in ethanolic solution. One of the compounds has a tetrahedral structure while the remaining compounds have polymeric octahedral structures. The i
A~tract---Complexes have been prepared by the reactions of anthranilamide with the chlorides of cobalt, nickel and copper in ethanolic solution, and of 2,2-bis(acrylamido)acetic acid with the carbonates of those elements in aqueous solution. All compounds have octahedral structures. Initial decompos
Complexes have been prepared by the reactions of 2,2'-biquinoline with the chlorides of cobalt, nickel and copper in ethanolic solution. The complexes have stoichiometry MLCI, where M = Co'+, Nil+, Cu\*+ and L is 2,2'-biquinoline. The cobalt and copper complexes have tetrahedral structures while the