Spectral and magnetic properties of some chloro and bromo transition metal complexes of isonicotinamide and a study of their performance as colouring materials for poly(vinyl chloride)
โ Scribed by J.R. Allan; G.M. Baillie; H.J. Bowley; D.L. Gerrard
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 335 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0014-3057
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The chloro complexes of cobalt, nickel and copper with 2-phenyl-4-quinoline carboxylic acid have stoichiometry MLCI 2 . The complexes which are polymeric have a stereochemistry in which the metal ion is in a six coordinate environment. The decompositions of the complexes have been studied by thermog
Complexes have been prepared by the reactions of 2,2'-biquinoline with the chlorides of cobalt, nickel and copper in ethanolic solution. The complexes have stoichiometry MLCI, where M = Co'+, Nil+, Cu\*+ and L is 2,2'-biquinoline. The cobalt and copper complexes have tetrahedral structures while the