A Study of the Nitrogen NMR Spectra of Azoles and their Solvent Dependence
✍ Scribed by Jaszuński, Michał; Mikkelsen, Kurt V.; Rizzo, Antonio; Witanowski, Michał
- Book ID
- 126962589
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 68 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
High-precision nitrogen NMR shieldings, bulk susceptibility corrected, are reported for the N-methyl derivatives of the two existing isomeric tetrazoles (I, II) in a variety of solvents which represent a wide range of solvent properties from the point of view of polarity as well as hydrogen bond don
3 NMR data are reported for 42 szoles, taken mostly at a standard concentration and in a common solvent (0.5 M dimethyl sulfoxide with a 0.01 M increment of Cr(acac), for each nitrogen atom present). Signal assignments were assisted by comparison witb ' " N line widths, the use of zJ(15N'H) coupling
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Chemical shifts and coupling constants are reported for seven azole derivatives (iidamles, triazoles and their b e m derivatives), their quaternary salts and the corresponding dicyanomethylides. The assignment of the heterocyclic carbons is based on couplings with the N-methyl group. Compared with n