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A 15N NMR study of some azoles

✍ Scribed by L. Stefaniak; John D. Roberts; M. Witanowski; G. A. Webb

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 334 KB
Volume: 22
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270220404

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✦ Synopsis

3 NMR data are reported for 42 szoles, taken mostly at a standard concentration and in a common solvent (0.5 M dimethyl sulfoxide with a 0.01 M increment of Cr(acac), for each nitrogen atom present). Signal assignments were assisted by comparison witb ' " N line widths, the use of zJ(15N'H) couplings, and shielding calculations obtained by the INDO/S-SOS approach. The generally large Merences in nitrogen-shielding changes permitted rather facile shift assignments.

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